Engineering Chemistry Project Report: 3 Key Materials in Civil Engineering

TRIBHUVAN UNIVERSITY

INSTITUTE OF ENGINEERING

PULCHOWK CAMPUS

A REPORT SUBMITTED FOR THE PARTIAL FULFILMENT OF THE REQUIREMENT FOR THE SEMISTER IN

ENGINEERING CHEMISTRY

ROLE OF PAINTS, LUBRICANTS AND EXPLOSIVES IN CIVIL ENGINEERING FIELD

SUBMITTED BY:

ACKNOWLEDGEMENT

Dear Sir,

I am writing to express my sincere gratitude for your guidance and support during my chemistry project. Your expertise and knowledge were invaluable and helped me to successfully complete my research. I would also like to thank you for the time you took to provide resources and review my work. Your encouragement throughout the process was greatly appreciated and played a crucial role in my success. I am grateful for the experience and knowledge I gained from working on this project, and I am thankful to have had the opportunity to learn from such an experienced and respected mentor.

I would also like to extend a special thanks to my friend, Binod Pant, who provided invaluable assistance during the preparation of the report. His support and collaboration were instrumental in shaping the final outcome of the project.

Thank you again for your help and support.



Sincerely,
Saroj Rai
080bce_ _
IOE, PULCHOWK CAMPUS

ABSTRACT – Engineering Chemistry Project Report Summary

This Engineering Chemistry Project Report explores the fundamental aspects and practical applications of paints, lubricants, and explosives within the field of civil engineering.

In the chapter on paints, we delve into their role in protecting surfaces from environmental degradation while enhancing aesthetic appeal. The report outlines the functions, characteristics, ingredients, types, and applications of paints, providing a comprehensive understanding of their significance in interior design and surface protection.

Moving on to lubricants, the report discusses their crucial role in reducing friction between moving surfaces, thereby enhancing mechanical efficiency and longevity. It details the functions, characteristics, classification, and applications of lubricants, highlighting their diverse uses in various civil engineering applications, from concrete formwork release to hydraulic systems.

Finally, the report explores explosives, elucidating their rapid chemical reactions and release of energy upon detonation. It outlines the characteristics, classification, and applications of explosives, emphasizing their importance in controlled demolition, quarrying, mining, and other civil engineering operations.

Overall, this Engineering Chemistry Project Report serves as a comprehensive guide to the principles and applications of paints, lubricants, and explosives, offering valuable insights for professionals and enthusiasts in the field of civil engineering.

1. PAINTS

1.1 Introduction to Paints in this Engineering Chemistry Project Report

Paints are used to protect metals, timber or plastered surfaces from the corrosive effects of weather, heat, moisture or gases etc. and also to improve their appearance.

1.2 Functions of Paint

  • It protects wood from decaying.
  • It prevents corrosion of metals.
  • It renders surface hygienically safe and clean.
  • It gives decorative and attractive appearance to the surface.
  • It also protects the surface from harmful effects of atmospheric agencies.

1.3 Characteristics of an Ideal Paint

  • The paint should be cheap.
  • It should be easy and harmless to the user.
  • It should retain its original color for a long time.
  • It should be able to cover maximum area of the surface with minimum quantities.
  • The painted surface should dry neither too slowly nor too rapidly.
  • When applied, the paint should form a thin uniform film on painted surface.
  • The paint should form a hard and durable coat on the painted surface.
  • The paint should not peel off from painted surface.
  • It should be good fire and moisture resistant.
  • The painted surface should not show any cracks.
  • The painted surface should possess attractive and decorative pleasing appearance.
  • Atmospheric agencies should not be able to affect the painted surface.

1.4 Ingredients of Paints

The ingredients of paints can vary depending on the type of paint (such as oil-based, water-based, or solvent-based) and the desired properties. However, here are the common ingredients found in many types of paints:

1.4.1 Pigments

These are finely ground solid particles that provide color and opacity to the paint. Pigments can be organic or inorganic compounds and are responsible for the paint’s visual appearance.

1.4.2 Binders

Binders are substances that hold the pigment particles together and adhere them to the surface after the paint is applied. They form a continuous film when the paint dries, providing durability and protection. Common binders include:

  • Acrylic polymers
  • Alkyd resins
  • Latex (synthetic polymers)
  • Linseed oil (in oil-based paints)
  • Epoxy resins (in specialty paints)
1.4.3 Solvents

Solvents are liquids used to dissolve or disperse the pigment and binder components to create a smooth consistency. They evaporate as the paint dries, leaving behind a solid, dry film of pigment and binder. Common solvents include:

  • Water (in water-based paints)
  • Mineral spirits
  • Turpentine
  • White spirits
1.4.4 Additives

Additives are additional substances mixed into the paint to modify its properties or enhance performance. Some common additives include:

  • Thickeners or rheology modifiers to adjust viscosity
  • Drying agents to speed up drying time
  • Antifungal and antibacterial agents to prevent mold and mildew growth
  • UV inhibitors to protect against sunlight damage
  • Surfactants to improve wetting and dispersion
  • Fillers or extenders to enhance volume and improve coverage

1.5 Types of Paints

  • Latex Paint: Also known as acrylic paint, latex paint is water-based and dries quickly. It’s easy to clean up with water, has low odor, and is commonly used for interior walls and ceilings.
  • Oil-Based Paint: Made with an oil binder, oil-based paint takes longer to dry but offers a durable and smooth finish. It’s suitable for woodwork, metal surfaces, and areas prone to high wear and tear.
  • Enamel Paint: Enamel paints are highly durable and have a hard, glossy finish. They’re often used for metal surfaces, trim, and furniture.
  • Chalk Paint: Chalk paint has a matte finish and is known for its ease of use and ability to adhere to various surfaces without extensive preparation. It’s popular for furniture refinishing and decorative projects.
  • Primer Paint: Primer paint is used as a base coat before applying the final paint layer. It helps improve adhesion, seals porous surfaces, and enhances the durability and coverage of the topcoat.
  • Epoxy Paint: Epoxy paint consists of epoxy resin and a hardener, resulting in a tough and durable finish. It’s commonly used for industrial floors, garage floors, and metal surfaces requiring chemical and abrasion resistance.
  • Acrylic Paint: Acrylic paint is versatile and available in both water-based and solvent-based formulas. It dries quickly, has excellent color retention, and can be used on various surfaces including canvas, wood, and plastic.
  • Spray Paint: Spray paint is applied using an aerosol can and is convenient for covering large areas or achieving even coats on irregular surfaces. It’s available in various finishes and can be used indoors or outdoors.

1.6 Application of Paints

Paints play a crucial role in interior design, offering versatility, aesthetics, and protection to various surfaces within a space. Here are some common applications of paints in interior design:

  • Wall Finishes: One of the primary uses of paint in interior design is to coat and decorate walls. Different types of paint finish such as matte, satin, eggshell, and glossy can be chosen based on the desired aesthetic and functionality. Paints can transform the mood and ambiance of a room, making it appear spacious, cozy, vibrant, or sophisticated.
  • Ceilings: Paints are applied to ceilings to enhance the overall look of a room. Ceiling paints are typically formulated to minimize splatter and ensure uniform coverage. Light-colored paints are often used to create an illusion of height and space, while darker colors can add warmth and intimacy to large rooms.
  • Trim and Moldings: Paints are used to highlight architectural details such as baseboards, crown moldings, and door frames. Contrasting or coordinating colors can be applied to trim to create visual interest and define the edges of a room.
  • Furniture Refinishing: Paints are utilized to refurbish and revitalize furniture pieces. Old or outdated furniture can be transformed with a fresh coat of paint, allowing for customization and integration into the overall design scheme of a space.
  • Accent Walls: Paints are often employed to create focal points within a room by painting one wall in a different color or texture than the rest. Accent walls draw attention and add depth to a space, serving as a backdrop for artwork, furniture, or architectural features.
  • Decorative Effects: Paints can be used to achieve various decorative effects such as faux finishes, stenciling, and murals. These techniques allow for artistic expression and customization, enabling individuals to personalize their living spaces according to their preferences and style.
  • Functional Coatings: Specialized paints are used for functional purposes such as moisture resistance in bathrooms and kitchens, stain resistance in high-traffic areas, and heat resistance around fireplaces and stoves. These coatings provide durability and longevity to surfaces while maintaining their aesthetic appeal.

2. LUBRICANTS

2.1 Introduction

A chemical substance introduced between two moving surfaces to reduce heat generated due to friction. The process of reducing frictional resistance between moving / sliding surfaces by introduction of lubricants in between them is known as Lubrication.

2.2 Functions of a Lubricant

  • It reduces wearing, tearing and surface deformation of the two substances moving in contact.
  • It reduces the expansion of metal by local frictional heat.

2.3 Characteristics of Good Lubricants

  • Low Friction Coefficient: The lubricant should exhibit a low coefficient of friction between the surfaces it is lubricating.
  • High Lubricity: Lubricity refers to the ability of the lubricant to form a durable film or layer between the surfaces in contact.
  • Viscosity: The lubricant should have an appropriate viscosity for the application.
  • Chemical Stability: An ideal lubricant should be chemically stable under the operating conditions it’s subjected to.
  • Compatibility: The lubricant should be compatible with the materials of the components it lubricates.
  • Non-Corrosive: It should not promote corrosion of the materials it comes into contact with.
  • Temperature Stability: The lubricant should maintain its properties across a range of temperatures.
  • Water Resistance: Depending on the application, a lubricant may need to resist the detrimental effects of water.
  • Cost-effectiveness: An ideal lubricant should provide excellent performance relative to its cost.

2.4 Classification of Lubricants

  1. Liquid lubricants or Lubricating oils (e.g., Mineral oil, Petroleum oil)
  2. Semi–solid lubricants (e.g., Greases, Vaseline)
  3. Solid lubricants (e.g., Molybdenum sulphide, Graphite)
  4. Synthetic lubricants (e.g., Polypropylene, Silicones)
2.4.1 Liquid lubricants or lubricating oils

The lubricants which are in liquid state such as animal and vegetable oils, mineral or petroleum oils are called lubricating oils. They reduce friction and wear by providing a continuous fluid film between moving surfaces.

2.4.2 Semi-Solid Lubricants or Greases

Greases are semi-solid lubricants prepared by dispersion of soaps into liquid lubricating oil. They have higher frictional resistance than oils, so can support much heavier loads at lower speeds.

2.4.3 Solid Lubricants

Solid lubricants or dry lubricants are those which despite being in solid phase are able to reduce friction between two surfaces sliding against each other without need for a liquid media. They are used where oils or greases would be contaminated or cannot be used due to high temperatures.

2.4.4 Synthetic Lubricants

These are lubricants synthesized for application at abnormal conditions like extremely high temperature or in chemically reactive atmospheres. They possess high viscosity index, high flash points, and high thermal stability.

2.5 Application of Lubricants

  • Concrete Formwork Release: Lubricants are applied to formwork surfaces to prevent concrete from sticking.
  • Pile Driving: Lubricants reduce friction between the pile and surrounding soil or rock.
  • Tunneling Operations: Lubricants are applied to tunnel boring machine (TBM) cutting tools to reduce friction and heat.
  • Cable Pulling: Lubricants reduce friction during cable pulling operations in underground conduits.
  • Asphalt Production and Application: Lubricants are added to asphalt mixes to improve workability.
  • Expansion Joints and Bearings: Lubricants are used in bridges and dams to allow for smooth movement.
  • Hydraulic Systems: Lubricants are essential for the smooth operation of hydraulic systems in construction equipment.

3. EXPLOSIVES

3.1 Introduction

An explosive is a chemical compound or a mixture which on detonation undergoes a very rapid chemical reaction and explodes with a large amount of potential energy released in the form of heat, light, sound as well as large volume of gases are release. Since explosive reactions are exothermal the gases released are heated to high temperature so generate a high pressure on the surrounded.

3.2 Characteristics of an Ideal Explosive

  • High energy output: An ideal explosive should release a large amount of energy rapidly upon detonation.
  • Stability: It should be stable under normal storage and handling conditions.
  • Sensitivity: It should be sensitive to initiation by a reliable and controllable stimulus.
  • Controlled detonation: The explosive should detonate predictably and reliably under controlled conditions.
  • High detonation velocity: It should propagate a shock wave at a high velocity.
  • Versatility: An ideal explosive should be adaptable for various applications.
  • Cost-effectiveness: It should be cost-effective to produce, procure, and use.

3.3 Classification of Explosives

Explosives are classified as Primary Explosives and Secondary explosives.

3.3.1 Primary Explosives (Initiators or detonators)

These are highly sensitive explosives which explode on receiving a slight shock or by fire so must be handled with care. These are mainly used in small quantities to start or initiate the explosion of the main explosive. Example: Lead azide (PbN₆), Diazo dinitrophenol (DDNP).

3.3.2 Secondary Explosives

Secondary Explosives are further classified as low explosives and high explosives.

a. Low Explosives

These explosives simply burn and they do not explode violently. The chemical reaction taking place is comparatively slow. Example: Gun powder or Black powder – is a mixture of 75% KNO₃, 15% charcoal and 10% Sulphur.

10KNO₃ + 3S + 8C ⟶ 3K₂SO₄ + 2K₂CO₃ + 6CO₂ + 5N₂
b. High Explosives

High explosives have high energy content but may be quite stable and insensitive to fire and mechanical shocks. Generally, a primary explosive is used to initiate their explosion. Example: TNT, GTN, RDX, Dynamite.

Trinitrotoluene (TNT): It is a faint yellow crystalline solid, relatively insensitive to shock and cannot be exploded without a detonator. It is prepared by the nitration of Toluene.

C₇H₈ + 3HNO₃ ⟶ C₇H₅N₃O₆ + 3H₂O

Glyceryl trinitrate (GTN): Also known as Nitroglycerin, it is a pale yellow oily liquid which explodes on receiving small detonation. It is prepared by adding glycerol to a mixture of sulfuric and nitric acid.

C₃H₅(OH)₃ + 3HNO₃ ⟶ C₃H₅(ONO₂)₃ + 3H₂O

Plastic Explosive: These are combinations of explosives in a soft, plastic state that can be hand-molded into various shapes. They are prepared by mixing a high explosive with wax or oil.

3.4 Application of Explosives

  • Demolition: Used for controlled demolition of structures to make way for new construction.
  • Quarrying and Mining: Used to break up large masses of rock and extract valuable minerals.
  • Excavation: Used for large-scale projects such as highway construction and tunneling in rocky terrain.
  • Rock Fragmentation: Used to fragment large rocks into smaller, more manageable pieces for construction.
  • Dredging: Used in underwater engineering projects to remove sediment and obstructions.
  • Seismic Exploration: Used in geotechnical engineering to study subsurface characteristics.
  • Avalanche Control: Used to trigger controlled avalanches to mitigate risks in mountainous regions.

REFERENCES

  1. Book
    1. Pant, H. R., & Mukhiya, T. (2024). Engineering Chemistry (1st ed.). Asmita Publication.
  2. Website
    1. Wikipedia contributors. (n.d.). *Paint*. Wikipedia. Retrieved October 4, 2025, from https://en.wikipedia.org/wiki/Paint
    2. Wikipedia contributors. (n.d.). *Lubricant*. Wikipedia. Retrieved October 4, 2025, from https://en.wikipedia.org/wiki/Lubricant
    3. Wikipedia contributors. (n.d.). *Explosive*. Wikipedia. Retrieved October 4, 2025, from https://en.wikipedia.org/wiki/Explosive
    4. IntechOpen. (2016). *Title of chapter*. IntechOpen. https://www.intechopen.com/chapters/44639
    5. Studocu. (n.d.). *Unit 5 paints and varnishes in building materials for the basic engineering in building*. Studocu. Retrieved October 4, 2025, from https://www.studocu.com/in/document/technical-university-of-kenya/beng-civil-engineering/unit-5-paints-and-varnishes-in-building-materials-for-the-basic-engineering-in-building/32446107
  3. Portable Document Format (PDF)
    1. RMS. (n.d.). *Lubricants*. [Unpublished manuscript], Department of Engineering, IOE.
    2. RR. (n.d.). *Explosives*. [Unpublished manuscript], Department of Engineering, IOE.
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